Source: Extra Practice

A 2.0 M2.0\text{ M} aqueous solution of NaOHNaOH (molar mass = 40 g/mol40\text{ g/mol}) has a density of 1.28 g/mL1.28\text{ g/mL}. Calculate the molality (mm) of the solution.

Options

Option A is correct

1.67 m1.67\text{ m}

Option B

1.56 m1.56\text{ m}

Option C

2.00 m2.00\text{ m}

Option D

1.20 m1.20\text{ m}

Explanation

To solve for molality (mm), we follow these steps:

  1. Definitions: Molarity (MM) is moles of solute per liter of solution. Molality (mm) is moles of solute per kilogram of solvent.

  2. Assumption: Assume we have 1 L1\text{ L} (1000 mL1000\text{ mL}) of the solution.

    • Moles of solute (NaOHNaOH) = 2.0 moles2.0\text{ moles} (since it is a 2.0 M2.0\text{ M} solution).
    • Mass of solute = moles×molar mass=2.0 mol×40 g/mol=80 g\text{moles} \times \text{molar mass} = 2.0\text{ mol} \times 40\text{ g/mol} = 80\text{ g}.
  3. Mass of Solution: Using density (d=1.28 g/mLd = 1.28\text{ g/mL}),

    • Mass of 1000 mL1000\text{ mL} solution = 1000 mL×1.28 g/mL=1280 g1000\text{ mL} \times 1.28\text{ g/mL} = 1280\text{ g}.
  4. Mass of Solvent:

    • Mass of solvent (water) = Total mass of solution - Mass of solute
    • Mass of solvent = 1280 g80 g=1200 g=1.2 kg1280\text{ g} - 80\text{ g} = 1200\text{ g} = 1.2\text{ kg}.
  5. Molality Calculation:

    • m=moles of solutemass of solvent in kg=2.0 mol1.2 kg1.67 mol/kgm = \frac{\text{moles of solute}}{\text{mass of solvent in kg}} = \frac{2.0\text{ mol}}{1.2\text{ kg}} \approx 1.67\text{ mol/kg}.

Alternative Formula: m=1000×M1000×dM×M2=1000×21000×1.282×40=20001200=1.67 mm = \frac{1000 \times M}{1000 \times d - M \times M_2} = \frac{1000 \times 2}{1000 \times 1.28 - 2 \times 40} = \frac{2000}{1200} = 1.67\text{ m}.

Other options are incorrect because they arise from common errors: 2.00 m2.00\text{ m} wrongly assumes molality equals molarity; 1.56 m1.56\text{ m} or 1.20 m1.20\text{ m} result from calculation errors such as forgetting to subtract the solute mass from the total solution mass.