To solve for molality (m), we follow these steps:
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Definitions: Molarity (M) is moles of solute per liter of solution. Molality (m) is moles of solute per kilogram of solvent.
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Assumption: Assume we have 1 L (1000 mL) of the solution.
- Moles of solute (NaOH) = 2.0 moles (since it is a 2.0 M solution).
- Mass of solute = moles×molar mass=2.0 mol×40 g/mol=80 g.
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Mass of Solution: Using density (d=1.28 g/mL),
- Mass of 1000 mL solution = 1000 mL×1.28 g/mL=1280 g.
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Mass of Solvent:
- Mass of solvent (water) = Total mass of solution - Mass of solute
- Mass of solvent = 1280 g−80 g=1200 g=1.2 kg.
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Molality Calculation:
- m=mass of solvent in kgmoles of solute=1.2 kg2.0 mol≈1.67 mol/kg.
Alternative Formula: m=1000×d−M×M21000×M=1000×1.28−2×401000×2=12002000=1.67 m.
Other options are incorrect because they arise from common errors: 2.00 m wrongly assumes molality equals molarity; 1.56 m or 1.20 m result from calculation errors such as forgetting to subtract the solute mass from the total solution mass.