Source: Extra Practice

If a copper coin is dipped into a solution of silver nitrate, over time, a shiny greyish-white coating appears on the copper coin, and the solution turns bluish. Explain the observation based on the reactivity of metals.

Options

Option A

Silver is more reactive than copper, so copper displaces silver.

Option B is correct

Copper is more reactive than silver, so copper displaces silver from its salt solution.

Option C

Both copper and silver are equally reactive, causing a simple mixing.

Option D

This is a physical change, where silver just settles on the copper.

Explanation

This observation is due to a displacement reaction. Copper is more reactive than silver. When a copper coin is dipped into silver nitrate solution (AgNO3AgNO_3), the more reactive copper displaces the less reactive silver from its salt solution. The silver metal gets deposited on the copper coin, appearing as a shiny greyish-white coating. Simultaneously, copper goes into the solution to form copper nitrate (Cu(NO3)2Cu(NO_3)_2), which is blue in colour, causing the solution to turn bluish. This demonstrates the reactivity series of metals, where a more reactive metal can displace a less reactive metal from its compound.